Chemistry MDCAT

Organic, inorganic & physical chemistry MCQs

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Chemistry

MDCAT Chemistry MCQs — organic, inorganic & physical chemistry

305 MCQs Page 6 of 16
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A. -2
B. +1
D. -1
Answer: In peroxides such as H2O2, oxygen has an oxidation state of -1 instead of the usual -2.
A. NaCl
B. Na2CO3
C. NaHCO3
D. NaNO2
Answer: Sodium nitrite (NaNO2) is used as a preservative in cured meats to prevent bacterial growth.
A. CH3OH
B. CH3COOH
C. CH3CHO
D. CH3OCH3
Answer: Dimethyl ether (CH3OCH3) has an oxygen atom bonded to two alkyl groups, characterizing an ether.
A. Ethanol
B. Chloroform
C. Acetone
D. Iodoform
Answer: Iodoform (CHI3) has mild antiseptic properties and is used on wounds and burns.
A. Li
B. B
C. C
D. Be
Answer: Be has a filled 2s orbital, making it more stable and harder to ionize than adjacent elements.
A. sp
B. sp2
C. sp3
D. sp3d
Answer: Carbon in CH4 forms four sigma bonds with no lone pairs, giving sp3 hybridization and tetrahedral geometry.
A. 6
B. 8
C. 14
D. 10
Answer: Carbon-14 has atomic number 6 (protons = 6) and mass number 14. Neutrons = 14 - 6 = 8.
A. Principal quantum number (n)
B. Azimuthal quantum number (l)
C. Magnetic quantum number (ml)
D. Spin quantum number (ms)
Answer: The azimuthal quantum number (l) determines the shape of an orbital: l=0 is s (spherical), l=1 is p (dumbbell), etc.
A. Sodium (Na)
B. Magnesium (Mg)
C. Oxygen (O)
D. Chlorine (Cl)
Answer: Oxygen has an electronegativity of 3.44 on the Pauling scale, which is higher than Na (0.93), Mg (1.31), and Cl (3.16).
A. C6H12O6
B. C6H10O5
C. C12H22O11
D. CH2O
Answer: Glucose is a monosaccharide with the molecular formula C6H12O6, containing six carbon atoms, twelve hydrogen atoms, and six oxygen atoms.
A. Covalent bonding
B. Ionic bonding
C. Metallic bonding
D. Hydrogen bonding
Answer: NaCl is formed by the transfer of an electron from Na to Cl, creating Na+ and Cl- ions held together by electrostatic (ionic) forces.
A. +3
B. +4
C. +6
D. +7
Answer: In K2Cr2O7: 2(+1) + 2(Cr) + 7(-2) = 0, so 2Cr = 12, Cr = +6.
A. Boyle\'s law
B. Charles\'s law
C. Avogadro\'s law
D. Dalton\'s law
Answer: Charles\'s law states V ∝ T (at constant P and n), meaning volume increases linearly with absolute temperature.
A. 1
B. 2
C. 3
D. 4
Answer: HCl is a strong acid that fully dissociates. [H+] = 0.001 M = 10^-3, so pH = -log(10^-3) = 3.
A. Bromine (Br)
B. Chlorine (Cl)
C. Iodine (I)
D. Fluorine (F)
Answer: The configuration [Ar] 3d10 4s2 4p5 has 35 electrons, which corresponds to Bromine (Z = 35).
A. Methanol
B. Ethanol
C. Propanol
D. Ethanal
Answer: CH3-CH2-OH has a two-carbon chain with a hydroxyl group, so its IUPAC name is ethanol (ethan-1-ol).
A. NH3
B. OH-
C. BF3
D. CH3O-
Answer: BF3 is electron-deficient (boron has only 6 electrons) and can accept an electron pair, making it an electrophile.
A. 4 sigma, 1 pi
B. 5 sigma, 1 pi
C. 4 sigma, 2 pi
D. 5 sigma, 0 pi
Answer: Ethene has 4 C-H sigma bonds + 1 C-C sigma bond = 5 sigma bonds, and 1 C=C pi bond.
A. 0.1 M NaCl
B. 0.1 M glucose
C. 0.1 M CaCl2
D. 0.1 M urea
Answer: Boiling point elevation depends on the number of solute particles. CaCl2 dissociates into 3 ions (i=3), producing the greatest elevation.
A. +1.00 V
B. 0.00 V
C. -1.00 V
D. +0.76 V
Answer: The Standard Hydrogen Electrode (SHE) is assigned a potential of exactly 0.00 V by convention and serves as the reference for all other electrodes.
4 5 6 7 8